Only in very small crystals, which are hexagonal or triangular shaped, and may also be tabular or pseudocubic. Also grainy, as fibrous crusts, in nodules, and in thin, hexagonal scales.
Natrojarosite has been found in Lavrion, Greece; the Francon Quarry, Montreal, Quebec, Canada; Rapid Creek area, Yukon Territory, Canada; and Palos Verdes Hills, Los Angeles Co., California.
Natrojarosite's crystal forms combined with its color easily identify it. However, poorly crystallized examples and massive forms of Natrojarosite may be difficult to distinguish from other minerals, such as Limonite. Natrojarosite is also indistinguishable from its isomorphous mineral Jarosite by ordinary methods.