Anorthoclase is the intermediary member of the Albite-Sanidine series. It is interesting to note that this mineral series contains two end members crystallizing in different crystal systems. Albite crystallizes in the triclinic system, whereas Sanidine crystallizes in the monoclinic system.

When Anorthoclase forms, its atoms form in a specific arrangement. This arrangement of the atoms forms the crystal structure of the mineral. Depending on the environment it forms in, it will either form a monoclinic or triclinic crystal. If it forms a monoclinic crystal, it leans toward Sanidine in regard to its crystal structure, and if it forms in the triclinic system, it leans toward Albite. (For this reason, Anorthoclase crystals can either be triclinic or monoclinic, although the tendency is usually toward triclinic.) The scientific classification of Sanidine, Anorthoclase, and Albite can only be determined with x-ray analysis. However, certain localities produce known examples of these particular Feldspars, in which case the mineral type can be determined without complex analysis. (Click here for more detailed information on the crystal structure of the Feldspars.)